merck-100988-725b47.jpg
merck-100988-725b47.jpg

MERCK 100988.2500 1-Butanol Emprove CAS No.71-36-3 (SD.M.100988.2500)

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MERCK 100988.2500 1-Butanol Emprove CAS No.71-36-3

 

Description
Catalogue Number 100988
Synonyms Butan-1-ol, n-Butyl alcohol, BuOH
Description 1-Butanol
Product Information
CAS number 71-36-3
EC index number 603-004-00-6
EC number 200-751-6
Grade ChP,NF
Hill Formula C₄H₁₀O
Chemical formula CH₃(CH₂)₃OH
Molar Mass 74.12 g/mol
HS Code 2905 13 00
Structure formula Image Structure formula Image
Quality Level MQ500
Physicochemical Information
Boiling point 116 - 118 °C (1013 hPa)
Density 0.811 g/cm3 (20 °C)
Explosion limit 1.4 - 11.3 %(V)
Flash point 35 °C
Ignition temperature 340 °C
Melting Point -90 °C
pH value 7 (70 g/l, H₂O, 20 °C)
Vapor pressure <10 hPa (20 °C)
Solubility 66 g/l
Toxicological Information
LD 50 oral LD50 Rat 790 mg/kg
LD 50 dermal LD50 Rabbit 3400 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s) H226: Flammable liquid and vapour.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
H336: May cause drowsiness or dizziness.
Precautionary Statement(s) P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal Word Danger
RTECS EO1400000
Storage class 3 Flammable liquids
WGK WGK 1 slightly hazardous to water
Disposal 1
Strongly contaminated halogen-free organic solvents: container A.
Safety Information
Categories of danger flammable, harmful, irritant
Storage and Shipping Information
Storage Store at +2°C to +30°C.
Transport Information
Declaration (railroad and road) ADR, RID UN 1120 , 3, III
Declaration (transport by air) IATA-DGR UN 1120 , 3, III
Declaration (transport by sea) IMDG-Code UN 1120 , 3, III
Specifications
Assay (GC) ≥ 99.5 %
Identity (IR) conforms
Identity (B) conforms
Relative density (d 25 °C/25 °C) 0.807 - 0.809
Acidity conforms
Distilling range (distills within a range of 1.5 °C) 116 - 119 °C
Aldehydes conforms
Ni (Nickel)* ≤ 0.05 ppm
Rh (Rhodium)* ≤ 0.05 ppm
Limit of Butyraldehyde, 2-Butanol, Isobutyl alcohol and Butyl ether (GC) conforms
Butyraldehyde (GC) ≤ 0.1 % (v/v)
2-Butanol (GC) ≤ 0.1 % (v/v)
2-Methylpropan-1-ol (GC) ≤ 0.1 % (v/v)
Butyl ether (GC) ≤ 0.2 % (v/v)
Related substances (GC) (total impurities) (ChP) conforms
Residual solvents class 3 (ICH Q3C) < 0,5 %
Other residual solvents (ICH Q3C) excluded by production process
Non-volatile matter ≤ 0.004
Evaporation residue ≤ 0.004
Water ≤ 0.1
Elemental impurity specifications have been set considering ICH Q3D (Guideline for Elemental Impurities).
Class 1-3 elements are not likely to be present above the ICH Q3D option 1 limit, unless specified and indicated (*).
Conforms to ChP, NF.
Global Trade Item Number
Catalogue Number GTIN
1009881000 04022536013565
1009882500 04022536013589
1009886025 04022536013619
1009886190 04054839384523
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