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MERCK

MERCK 106762.0010 Ninhydrin GR CAS No.485-47-2 (SD.M.106762.0010)

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MERCK 106762.0010 Ninhydrin GR CAS No.485-47-2

 
Description
Catalogue Number 106717
Replaces NX0325-5
Synonyms Nickel dichloride
Description Nickel(II) chloride hexahydrate
Product Information
CAS number 7791-20-0
EC index number 028-011-00-6
EC number 231-743-0
Grade ACS
Hill Formula Cl₂Ni * 6 H₂O
Chemical formula NiCl₂ * 6 H₂O
Molar Mass 237.69 g/mol
HS Code 2827 35 00
Quality Level MQ300
Physicochemical Information
Density 1.92 g/cm3 (anhydrous substance)
Melting Point 1001 °C (anhydrous substance),decomposes
pH value 4.9 (H₂O, 20 °C)
Bulk density 640 kg/m3
Solubility 2540 g/l
Toxicological Information
LD 50 oral LD50 Rat 186 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s) H301 + H331: Toxic if swallowed or if inhaled.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H341: Suspected of causing genetic defects.
H350i: May cause cancer by inhalation.
H360D: May damage the unborn child.
H372: Causes damage to organs through prolonged or repeated exposure if inhaled.
H410: Very toxic to aquatic life with long lasting effects.
Precautionary Statement(s) P202: Do not handle until all safety precautions have been read and understood.
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P302 + P352: IF ON SKIN: Wash with plenty of water.
P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
Signal Word Danger
RTECS QR6480000
Storage class 6.1D Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK WGK 3 highly hazardous to water
Disposal 15
Heavy metal-containing solutions and solids: container E. Stir Raney nickel (also: Urushibara nickel) in the form of an aqueous suspension into hydrochloric acid (Cat. No. 100312) until dissolved (container E). Neither Raney nickel itself nor any filter residues should be allowed to dry out, otherwise they will spontaneously ignite in air. In this context, heavy metal means any compound of antimony, arsenic, cadmium, chromium(VI), copper, lead, nickel and tin, as well as these subtances in metallic form, if they are classified as hazardous (acc. to AbfallverzeichnisV - Waste Catalogue Ordinance, Appendix 3). Other heavy metals should be collected separately.
Safety Information
Categories of danger carcinogenic, toxic for reproduction, toxic, irritant, mutagenic, sensitizing, dangerous for the environment
Storage and Shipping Information
Storage Store at +2°C to +30°C.
Transport Information
Declaration (railroad and road) ADR, RID UN 3288 , 6.1, III
Declaration (transport by air) IATA-DGR UN 3288 , 6.1, III
Declaration (transport by sea) IMDG-Code UN 3288 , 6.1, III
Specifications
Assay (complexometric) ≥ 98.0 %
Insoluble matter ≤ 0.005 %
Sulfate (SO₄) ≤ 0.005 %
Total nitrogen (N) ≤ 0.005 %
Ca (Calcium) ≤ 0.005 %
Co (Cobalt) ≤ 0.005 %
Cu (Copper) ≤ 0.001 %
Fe (Iron) ≤ 0.001 %
K (Potassium) ≤ 0.01 %
Mg (Magnesium) ≤ 0.01 %
Mn (Manganese) ≤ 0.002 %
Na (Sodium) ≤ 0.01 %
Pb (Lead) ≤ 0.002 %
Zn (Zinc) ≤ 0.001 %
conforms to ACS
Global Trade Item Number
Catalogue Number GTIN
1067170250 04022536081380
1067171000 04022536081397
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