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MERCK

MERCK 807250.0250 Phenylenediamine for Synthesis (SD.M.807250.0250)

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MERCK 807250.0250 Phenylenediamine for Synthesis

 
Description
Catalogue Number 807250
Description Phenylhydrazine
Product Information
CAS number 100-63-0
EC index number 612-023-00-9
EC number 202-873-5
Hill Formula C₆H₈N₂
Chemical formula C₆H₅NHNH₂
Molar Mass 108.14 g/mol
HS Code 2928 00 90
Structure formula Image Structure formula Image
Quality Level MQ200
Applications
Application Phenylhydrazine for synthesis. CAS 100-63-0, EC Number 202-873-5, chemical formula C₆H₅NHNH₂.
Physicochemical Information
Boiling point 244 °C (1013 hPa)
Density 1.099 g/cm3
Explosion limit 1.1 %(V)
Flash point 89 °C
Ignition temperature 195 °C
Melting Point 19 °C
Vapor pressure 1.35 hPa (60 °C)
Solubility 145 g/l
Toxicological Information
LD 50 oral LD50 Rat 188 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s) H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H341: Suspected of causing genetic defects.
H350: May cause cancer.
H372: Causes damage to organs through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
Precautionary Statement(s) P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P302 + P352 + P312: IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell.
P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal Word Danger
RTECS MV8925000
Storage class 6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK WGK 3 highly hazardous to water
Disposal 9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Safety Information
Categories of danger carcinogenic, toxic, irritant, sensitizing, dangerous for the environment, mutagenic
Storage and Shipping Information
Storage Store below +30°C.
Transport Information
Declaration (railroad and road) ADR, RID UN 2572 , 6.1, II
Declaration (transport by air) IATA-DGR UN 2572 , 6.1, II
Declaration (transport by sea) IMDG-Code UN 2572 , 6.1, II
Specifications
Assay (HClO₄) ≥ 97.0 %
Density (d 20 °C/ 4 °C) 1.096 - 1.099
Identity (IR) passes test
Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt.
Global Trade Item Number
Catalogue Number GTIN
8072500005 04022536394442
8072500250 04022536394459
8072501000 04022536394466
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