MERCK 100013.2500 Acetone EMPROVE® CAS No.67-64-1 (SD.M.100013.2500)

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MERCK 100013.2500 Acetone EMPROVE® CAS No.67-64-1

Description
Catalogue Number	100013
Synonyms	Dimethyl ketone, Propanone, 2-Propanone

Physicochemical Information
Boiling point	56.2 °C (1013 hPa)
Density	0.79 g/cm3 (20 °C)
Explosion limit	2.6 - 12.8 %(V)
Flash point	-17.0 °C
Ignition temperature	465 °C DIN 51794
Melting Point	-94.0 °C
pH value	5 - 6 (395 g/l, H₂O, 20 °C)
Vapor pressure	245.3 hPa (20.0 °C)
Water absorption	1000 g/kg

Toxicological Information
LD 50 oral	LD50 Rat 5800 mg/kg
LD 50 dermal	LD50 Rabbit 20000 mg/kg

Safety Information according to GHS
Hazard Statement(s)	H225: Highly flammable liquid and vapour. H319: Causes serious eye irritation. H336: May cause drowsiness or dizziness. EUH066: Repeated exposure may cause skin dryness or cracking.
Precautionary Statement(s)	P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P240: Ground and bond container and receiving equipment. P241: Use explosion-proof electrical/ ventilating/ lighting equipment. P242: Use non-sparking tools. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Signal Word	Danger
RTECS	AL3150000
Storage class	3 Flammable liquids
WGK	WGK 1 slightly hazardous to water
Disposal	1 Strongly contaminated halogen-free organic solvents: container A.

Safety Information
Categories of danger	highly flammable, irritant

Storage and Shipping Information
Storage	Store at +2°C to +30°C.

Transport Information
Declaration (railroad and road) ADR, RID	UN 1090 Aceton, 3, II
Declaration (transport by air) IATA-DGR	UN 1090 ACETONE, 3, II
Declaration (transport by sea) IMDG-Code	UN 1090 ACETONE, 3, II

Specifications
Assay (GC)	≥ 99.0 %
Identity (IR)	conforms
Identity B (Ph Eur)	conforms
Identity C (Ph Eur)	conforms
Identity B (NF)	conforms
Identity (JPE)	conforms
Water-insoluble substances	conforms
Appearance of solution	conforms
Acidity or alkalinity	conforms
Density (d 20 °C/20 °C)	0.790 - 0.793
Density (d 25 °C/25 °C)	≤ 0.789
Reducing substances	conforms
Readily oxidizable substances	conforms
Potassium permanganate-reducing substances	conforms
Phenole	conforms
Cu (Copper)*	≤ 0.05 ppm
Related substances (GC) (Methanol (Impurity A))	≤ 0.05 %
Related substances (GC) (2-Propanol (Impurity B))	≤ 0.05 %
Related substances (GC) (Benzene (Impurity C))	≤ 2 ppm
Related substances (GC) (other impurity)	≤ 0.05 %
Cyclohexane (residual solvent) (GC)	≤ 0.01 %
Other residual solvents (ICH Q3C)	excluded by the manufacturing process
Evaporation residue	≤ 0.0020 %
Water	≤ 0.3
Elemental impurity specifications have been set considering ICH Q3D (Guideline for Elemental Impurities). Class 1-3 elements are not likely to be present above the ICH Q3D option 1 limit, unless specified and indicated (*). Conforms to Ph Eur, BP, JPE, NF

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